Background
The detection of neuro metabolites such as glutamine+glutamate (Glu+Gln: Glx), glutathione (GSH), glycerophosphocholine (GPC), phosphorylethanolamine (PE), with two dimensional localised correlation spectroscopy (2D L-COSY) can be challenging due to their complex inherent chemical structure and low physiological concentrations1. We investigated if 2D L-COSY with initial short TE of 20ms can improve the detectability of metabolites compared with standard initial TE of 30ms thus improving the detection of metabolites.
Method
After ethics approval and informed consent, in-vivo MRS using initial TE values of 20ms and 30ms 2D L-COSY were performed in the same session on 3 Tesla MRI with 64Channel brain coil. Braino Phantom was used for in vitro and three healthy volunteers were enrolled for the in-vivo study. 2D L-COSY was acquired from the posterior cingulate gyrus from a 27cm3 voxel, first TEinitial of 30ms and then TEinitial of 20ms, TR 1.5sec, 8 averages, and 96 increments. Raw spectral data was processed with Felix software. The signal intensity of diagonal and cross peaks, as well as background noise, were measured for each experiment. Mean SNR (peak intensity/noise)3 of selected peaks, as well as % SNR differences, were calculated.
Results and Discussion
The mean and the percentage mean difference in peak SNR betweenTE20 and TE30 showed marked increase in SNR for TE20, both for the diagonal (N-acetyl aspartate, Creatine, Choline, myo Inositol and lipid) and cross peaks (GSH, GPC, PE, Glx and lysine). In vitro data showed similar trend in increasing SNR for all major diagonal and cross peaks, but to lesser extent than in vivo results. Initial TE is an important parameter as it determines the extent of signal loss depending on characteristic T2* values. 2D L-COSY with short TE of 20ms has potential in the improved detection of cross peaks from metabolites.
References